一、实验室简介
催化工艺与工程实验室:本研究团队根据催化反应工艺的过程特点,基于反应/工艺过程方面对催化剂的要求,结合化学反应的特点进行工业催化剂开发,在催化剂的生产放大方面已积累较多经验。同时,以催化剂反应动力学为基础,研发与催化剂特性相匹配的反应技术;以全流程模拟为基础,研发绿色工艺,为获取产业化依据和基础设计工程软件包奠定基础。
目前,本团队根据煤制合成天然气反应工艺的过程要求,已开发耐高温耐水热的甲烷化催化剂及相匹配的反应技术;基于厦门大学AM502催化剂的研究结果,本团队已基本掌握流化床工艺制备300 Kg/a碳纳米管技术中试放大技术;根据碳四产业链的特点,已开发一种正丁烯骨架异构催化剂,并在成泰化工5万吨/a装置上试用;并根据碳四行业的发展趋势,正在开发氧化酯化一步制MMA的反应技术;基于产品高附加值化的要求,我们对大宗化工(煤制乙醇、PBS涉及的丁二醇及丁二酸)、精细化学品(香料行业的蒎烯、农医药行业的硝基苯胺等)的加氢技术也已初步掌握。此外,针对环保的需求,开发系列低温高效的VOCs催化氧化催化剂,并应用于喷涂及印刷包装等行业;煤化工/医药等行业废水处理技术已通过中试实验,工业验证试验的顺利实现也指日可待。
二、课题组长
陈秉辉
工学博士,教授
厦门大学醇醚酯化工清洁生产国家工程实验室
电话:(0592)2185253、2185203(lab)
邮箱: chenbh@xmu.edu.cn
地址: 厦门大学(翔安)校区能源1号楼 厦门市翔安区翔安南路
个人简历:
2013.02 ~ 2018.08厦门大学化学化工学院化学工程与生物工程系主任
2010.01至今 醇醚酯化工清洁生产国家工程实验室副主任
2009.01~2013.01厦门大学化学化工学院工业催化与能源化工研究所所长
2008.02 至今厦门大学化学化工学院化学工程与生物工程系教授
2005.02~2008.01 英国大学学院生物工程国家实验室Research Fellow
2002.04~2005.01 英国帝国理工过程系统工程国家实验室Research Fellow
2001.01~2002.03 英国大学学院生物工程国家实验室博士后
1998.04~2000.12英国拉夫堡大学化工系博士后
1994.10~1998.04 英国利兹大学化工系博士
1984.07~1994.09 浙江大学化工系任助教、讲师
社会兼职:
中国化工学会 理事
福建省化工学会 秘书长
三、研究兴趣
3D打印材料;纳米材料的可控制备;金属原子尺度结构与催化剂特性的构效关系;多相催化反应工程;过程集成与优化;废弃物的资源化利用
四、发表文章
2016-2020
1. Aolin Lu, Hanlei Sun, Nuowei Zhang, Liming Che, Shiyao Shan, Jin Luo, Jinbao Zheng, Lefu Yang, Dong-Liang Peng, Chuan-Jian Zhong, Chen BH*(2019). Surface Partial-Charge-Tuned Enhancement of Catalytic Activity of Platinum Nanocatalysts for Toluene Oxidation. ACS Catalysis 97431-7442
2. Fen Wang, Jing-Cai Zhang, Zhi-Qiang Chen, Jing-Dong Lin, Wei-Zhen Li, Yong Wang Chen BH*(2019). Water-saving dry methanation for direct conversion of syngas to synthetic natural gas over robust Ni0.1Mg0.9Al2O4 catalyst. Journal of Catalysis 375: 466-477
3. CaoZhikai; Hu Tao; Guo JW; Xie Jianrong; Zhang NW; Zheng JB; Che Liming; Chen BH*(2019). Stable and facile ethanol synthesis from syngas in one reactor by tandem combination CuZnAl-HZSM-5, modified-H-Mordenite with CuZnAl catalyst. Fuel, 254: 115542–115547
4. Wang F, Zhang JC, Li WZ, Chen BH*(2019).Coke-resistant Au–Ni/MgAl2O4 catalyst for direct methanation of syngas. Journal of Energy Chemistry 39: 198–207
5. Fu JL, Yue QQ, Guo HZ, Ma CJ, Wen YY, Zhang H, Zhang NW,* Zheng YP, Zheng JB, and Chen BH* (2018).Constructing Pd/CeO2/C To Achieve High Leaching Resistance and Activity for Catalytic Wet Air Oxidation of Aqueous Amide.ACS Catalysis 8, 4980-4985
6. Fu JL, XiaoDW, Yue QQ, Geng LL, Fasan Paul,Zhang NW*, Zheng JB and Chen BH* (2018).Insights into the reaction mechanism of catalytic wet air oxidation of ammonia over bimetallic Ru-Cu catalyst. Topics in catalysis. 61(15-17), 1684–1693
7. Fu JL, XiaoDW, Yue QQ, Geng LL, Fasan Paul,Zhang NW*, Zheng JB and Chen BH* (2018).Insights into the reaction mechanism of catalytic wet air oxidation of ammonia over bimetallic Ru-Cu catalyst. Topics in catalysis. 61(15-17), 1684–1693
8. YangZ, Zhu HZ, Zhu HJ, Wang YB, Che LM, Yang ZQ, Fang J, Wu QH,Chen BH* (2018).Insights into the role of nanoalloy surface composition towardcatalytic acetone hydrogenation. Chem. Commun., 54, 8351-8354
9. YangZ, Chen WH, Zheng JB, YangZQ, NW, Zhong CJ,Chen BH* (2018).Efficientlow-temperature hydrogenation of acetone on bimetallic Pt-Ru/C catalyst. Journal of Catalysis 363: 52–62
10. Li YH, Chen SJ, Cai XH, Hong JQ, Wu XE, Xu YZ, Zou JJ, Chen BH*(2018). Rational design and prepare of hierarchical monolith through 3D printing for syngas methanation. Journal of Materials Chemistry A 6: 5695 – 5702
11. Zhang H , Zhang XG , Wei J, Wang C , Chen S , Sun HL , Wang YH , Chen BH ,Yang ZL, Wu DY, Li JF , Tian, ZQ (2017). Revealing the Role of Interfacial Properties on Catalytic Behaviors by in Situ Surface-Enhanced Raman Spectroscopy. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 139(30): 10339-10346
12. Zhang H , Wang C, Sun HL, Fu G, Chen S , Zhang YJ , Chen BH , Anema JR ,Yang ZL , Li JF , Tian, ZQ (2019). In situ dynamic tracking of heterogeneous nanocatalytic processes by shell-isolated nanoparticle-enhanced Raman spectroscopy. NATURE COMMUNICATIONS. 8: 15447
13. Ye, SS, Guo JW, Wang YB, Xie JR , Liu ZM , Zhang NW, Zheng JB, Cao ZK, Chen BH (2019). Effect of sodium content on the interaction between Ni and support and catalytic performance for syngas methanation over Ni/Zr-Yb-O catalysts. CHINESE JOURNAL OF CHEMICAL ENGINEERING. 27(11): 2705-2711
14. Cao ZK, Hu T, Guo JW , Xie JR , Zhang NW, Zheng JB , Che LM,Chen, BH (2019). Stable and facile ethanol synthesis from syngas in one reactor by tandem combination CuZnAl-HZSM-5, modified-H-Mordenite with CuZnAl catalyst. FUEL. 254.
15. Chen WH , Qiao GL, Liu HJ , Ye SS , Zheng JB , Zhang NW , Che LM, Chen BH. Templated coordination as a tool to increase the catalytic activity of metal aluminophosphates: the case of CoAPO-11. CATALYSIS SCIENCE & TECHNOLOGY. 9(17): 4505-4509
16. Lu AL, Sun HL , Zhang NW, Che LM , Shan SY , Luo J , Zheng JB , Yang LF , Peng DL , Zhong CJ , , Chen BH (2019). Surface Partial-Charge-Tuned Enhancement of Catalytic Activity of Platinum Nanocatalysts for Toluene Oxidation. ACS CATALYSIS. 9(8): 7431-7442
17. Geng LL , Gong JJ , Quo GL , Ye SS, Zheng JB , Zhang NW, Chen BH(2019). Effect of Metal Precursors on the Performance of Pt/SAPO-11 Catalysts for n-Dodecane Hydroisomerization. ACS OMEGA. 4(7): 12598-12605
18. 耿莉莉,蔡运安,许桂婷,陈秉辉. 合成气甲烷化过程模拟与分析[J]. 天然气化工(C1化学与化工),2019,44(02):72-79.
19. 郭家威,张蕾,南军,叶松寿,郑进保,陈秉辉. 1,4-丁炔二醇温和条件下Pd-Ni基加氢催化剂的研究[J]. 厦门大学学报(自然科学版),2019,58(05):661-668.
20. 郑弘光,陈文汉,水彩玲,郑进保,张诺伟,陈秉辉. 水蒸气改性H-FER分子筛在催化正丁烯骨架异构化反应中的应用[J]. 厦门大学学报(自然科学版),2019,58(05):669-677.
21. Fu JL, Xiao DW , Yue QQ , Geng LL , Fasan PO, Zhang NW, Zheng JB, Chen BH(2018). Insights into the Reaction Mechanism of Catalytic Wet Air Oxidation of Ammonia Over Bimetallic Ru-Cu Catalys. TOPICS IN CATALYSIS. 61(15-17): 1684-1693
22. Yang Z, Chen WH , Zheng JB , Yang ZQ , Zhang NW , Zhong CJ, Chen BH(2018). Efficient low-temperature hydrogenation of acetone on bimetallic Pt-Ru/C catalyst. JOURNAL OF CATALYSIS. 363: 52-62
23. Fu JL, Yue QQ, Guo HZ , Ma CJ , Wen YY , Zhang H , Zhang NW, Zheng YP , Zheng JB, Chen BH(2018). Constructing Pd/CeO2/C To Achieve High Leaching Resistance and Activity for Catalytic Wet Air Oxidation of Aqueous Amide. ACS CATALYSIS. 8(6): 4980
24. 王子丹,Hameed Sohaib,张诺伟,陈秉辉. PdNi/C低温高效催化湿式氧化无害化处理氨氮废水[J]. 厦门大学学报(自然科学版),2018,57(01):32-37.
25. 薛来奇,曹玲,陈秉辉,曹茂洪. 均四甲苯氧化制二酐宏观动力学分析[J]. 化学研究与应用,2018,30(05):696-700.
26. 耿莉莉,杨凯旭,张诺伟,陈秉辉. Ru和Cu协同催化湿式氧化处理氨氮废水[J]. 化工学报,2018,69(09):3869-3878.
27. 曹玲,薛来奇,陈秉辉,曹茂洪. 均四甲苯氧化制均苯四甲酸二酐热力学分析和宏观动力学的研究[J]. 化学反应工程与工艺,2018,34(05):467-472.
28. Ma CJ, Fu JL , Chen JX , Wen YY , Fasan PO , Zhang H, Zhang NW, Zheng JB, Chen BH(2017). Improving the Surface Properties of CeO2 by Dissolution of Ce3+ to Enhance the Performance for Catalytic Wet Air Oxidation of Phenol. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH. 56(32): 9090-9097
29. Ma CJ, Wen YY, Rong CL, Zhang NW, Zheng JB, Chen BH(2017). delta-MnO2 with an ultrahigh Mn4+ fraction is highly active and stable for catalytic wet air oxidation of phenol under mild conditions. CATALYSIS SCIENCE & TECHNOLOGY. 7(15): 3200-3204
30. Wang ZD, Hameed S , Wen YY , Zhang NW , Gai HJ , Zheng JB, Chen BH(2017). Platinum-nickel alloy nanoparticles supported on carbon for 3-pentanone hydrogenation. APPLIED SURFACE SCIENCE. 409: 29-34
31. Deng XL , Li MX , Zhang J , Hu XY , Zheng JB, Zhang NW, Chen BH(2017). Constructing nano-structure on silver/ceria-zirconia towards highly active and stable catalyst for soot oxidation. CHEMICAL ENGINEERING JOURNAL. 313: 544-555
32. Yang Z , Li D , Zhang L, Zheng JB, Zhang NW, Chen BH(2017). Deng XL , Li MX , Zhang J , Hu XY , Zheng JB, Zhang NW, Chen BH(2017). Constructing nano-structure on silver/ceria-zirconia towards highly active and stable catalyst for soot oxidation. CHEMCATCHEM. 9(2): 338-346
33. 邓湘玲,叶松寿,曹志凯,张诺伟,郑进保*,陈秉辉. Ag/Ce0.75Zr0.25O2 催化剂中 Ag 的负载量对碳烟燃烧活性的影响[J]. 化工学报,2017, 68(8): 3064-3070.
34. Zhang H, Liu XJ, Zhang NW, Zheng JB , Zheng YP, Li YH, Zhong CJ, Chen BH(2016). Construction of ultrafine and stable PtFe nano-alloy with ultra-low Pt loading for complete removal of CO in PROX at room temperature. APPLIED CATALYSIS B-ENVIRONMENTAL. 180: 237-245
35. Fu JL, Yang KX, Ma CJ, Zhang NW*, Gai HJ, Zheng JB and Chen BH* (2016). Bimetallic Ru-Cu as a highly active, selective and stable catalyst for catalytic wet oxidation of aqueous ammonia to nitrogen. Applied Catalysis B: Environmental 184: 216–222
36. Zhu LH,* Zheng JB, Yu CL, Zhang NW, Shu Q, Zhou H, Li YH, Chen BH* (2016) Effect of thermal treatment temperature of RuNi bimetallic nanocatalyst on its catalytic performance for benzene hydrogenation. RSC Advances 2016, 6, 13110-13119
37. Zhang H, Liu XJ, Zhang NW, Zheng JB*, Zheng YP, Li YH , Zhong CJ and Chen BH*. (2016). Construction of ultrafine and stable PtFe nano-alloy with ultra-low Pt loading for complete removal of CO in PROX at room temperature. Applied Catalysis B: Environmental 180: 237–245
38. 崔晶晶,李云华,陈秉辉. 离子液体[Hmim][CF_3SO_3]在木质素及其模型化合物生物降解中的应用[J]. 林产化学与工业,2016,36(04):1-6.
39. 吴斯侃,曹志凯,周华,陈秉辉. 一种用于二维稳态固定床的通用计算方法[J]. 厦门大学学报(自然科学版),2016,55(06):830-835
五、申请专利
2016-2020
1. 陈秉辉,唐旭光,郑进保,谢建榕,叶松寿,吴钊男.一种将煤层气脱氧后制多壁碳纳米管的方法[P].CN110921653A,2020-03-27.
2. 车黎明,张明正,陈秉辉,吴雪娥,周华.一种基于3D打印技术的仿生结构整体型催化剂的制备方法[P]. CN110901046A,2020-03-24.
3. 陈秉辉,张蕾,郑进保,李建军,张诺伟,叶松寿,谢建榕.一种碳碳双键的选择性加氢用催化剂及其制备方法和应用[P].CN108043431B,2020-04-03.
4. 陈秉辉,吴钊男,郑进保,曹志凯,谢建榕,张诺伟.一种用于制备多壁碳纳米管的催化剂及其制备方法与应用[P]. CN110961115A,2020-04-07.
5. 杨乐夫,田方方,蔡钒,贾献荣,张国玉,曹小红,伊晓东,陈秉辉,方维平.一种负载合金型碳烟氧化催化剂及其制备方法[P].CN108554406B,2020-04-24.
6. 陈秉辉,王芬,郑进保,张诺伟,叶松寿,谢建榕.一种甲烷化催化剂及其制备方法和应用[P]. CN109046380B,2020-05-05.
7. 陈秉辉,于颖,郑进保,张诺伟,叶松寿,李小飞.一种去除挥发性有机物的等离子体催化方法及装置[P]. CN107899420B,2020-05-05.
8. 郑进保,陈秉辉,王芬,叶松寿,张诺伟,刘香华.一种煤制天然气的制备方法[P]. CN107916150B,2020-05-05.
9. 张诺伟,陈冰冰,陈秉辉,耿莉莉,熊文婷,谢建榕,郑进保,叶松寿.一种湿式氧化催化剂及其制备方法和应用[P].:CN111135823A,2020-05-12.
10. 李云华,卢峻峰,陈秉辉.一种电催化甲醇制乙醇Co<sub>3</sub>ZnC催化剂及其应用[P]. CN108993557A,2018-12-14.
11. 陈秉辉,张诺伟,李建军,刘慧晶,郑进保.一种苯加氢制环己基苯的催化剂及其制备方法和应用[P].CN108993577A,2018-12-14.
12. 郑进保,陈秉辉,樊海燕,张蕾,万晶晶,张诺伟,胡程,谢建榕.一种丁炔二醇制丁二醇的高效加氢催化剂及其制备方法与应用[P].CN108993592A,2018-12-14.
13. 陈秉辉,张华,孙菡蕾,郑进保,张诺伟.一种脱除氢气中氧气的催化剂及其制备方法和应用[P].CN109012660A,2018-12-18.
14. 陈秉辉,万晶晶,郑进保,张蕾,樊海燕,张诺伟,巩建军,谢建榕.一种丁炔二醇半加氢双金属催化剂及其制备方法与应用[P]. CN109107583A,2019-01-01.
15. 陈秉辉,周杰,郑进保,李梦溪,陈文汉.一种用于催化正丁烯骨架异构化反应的镁碱沸石分子筛催化剂的制备方法[P].CN106829997B,2019-02-05.
16. 陈秉辉,胡涛,郭家威,张诺伟,谢建榕,郑进保.一种用于合成气一步法制乙醇并联产甲醇催化剂的制备方法及应用[P]. CN109331865A,2019-02-15.
17. 张诺伟,陈秉辉,郭浩哲,杨霁豪,陈冰冰,谢建榕,叶松寿,郑进保.一种催化湿式氧化催化剂及其制备方法和应用[P]. CN109465008A,2019-03-15.
18. 陈秉辉,宗子厚,郑进保,张诺伟,吴钊男,王明亮.一种利用异丁烯和甲醇制备3-甲基-3-丁烯-1-醇的方法[P].CN109574799A,2019-04-05.
19. 李云华,陈思静,陈秉辉.一种利用3D打印技术辅助结构化Ni-氧化铝/碳催化剂的制备方法[P]. CN107442127B,2019-07-23.
20. 陈秉辉,温瑶瑶,马长健,张诺伟,郑进保. 一种湿式氧化催化剂及其制备方法[P].CN106807364B,2019-08-06.
21. 陈秉辉,许梦东,郑进保,宗子厚,吴钊男,王明亮.一种一步氧化酯化法制甲基丙烯酸甲酯的催化剂及其制备方法和应用[P].CN110075835A,2019-08-02.
22. 陈秉辉,乔桂龙,郑进保,叶松寿,刘香华,江萍.一种耐水热复合催化剂及其制备方法和应用[P]. CN110252285A,2019-09-20.
23. 陈秉辉,张蕾,郑进保,胡涛,张诺伟,叶松寿,谢建榕.一种燕麦生物碱D及二氢燕麦碱D的分离分析方法[P].CN107941937B,2019-09-20.
24. 陈秉辉,江萍,郑进保,乔桂龙,叶松寿,李想,张诺伟.一种低温等离子体催化氧化VOCs的方法[P]. CN110339707A,2019-10-18.
25. 陈秉辉,张诺伟,岳青青,郑进保,符继乐.一种氨氮废水处理用催化剂及其制备方法和应用[P].CN107126962B,2019-10-25.
26. 陈秉辉,曹佃宇,郑进保,李小飞,张诺伟,叶松寿.二氧化碳等离子分解用催化剂及其制备方法、二氧化碳等离子分解用催化系统及其应用[P]. CN108031465B,2019-10-29.
27. 郑进保,胡程,陈秉辉,车黎明,张诺伟,谢建榕.一种2,4-二硝基苯胺加氢催化剂及其制备方法和应用[P].CN110560054A,2019-12-13.
28. 陈秉辉,朱慧娟,张诺伟,荣成礼,耿莉莉,郑进保.一种室温高效脱除空气或废水中甲醛的催化剂及其制备方法[P].福建:CN108246290A,2018-07-06.
29. 陈秉辉,郑泓光,郑进保,张诺伟,叶松寿.一种具有层状堆积结构的小晶粒FER分子筛的合成方法[P]. CN108862306A,2018-11-23.
30. 李云华,陈秉辉,陈思静,罗康.一种以可溶性糖为模板的介孔复合材料的制备方法[P]. CN106219554A,2016-12-14.
31. 杨乐夫,贾献荣,蔡钒,赖伟坤,张华,田方方,张国玉,伊晓东,陈秉辉,方维平.一种贵金属微区镶嵌型氧化物复合材料的制备方法[P]. CN106423040A,2017-02-22.
32. 李云华,陈秉辉.一种中孔硅胶的制备方法[P]. CN106395838A,2017-02-15.
33. 李云华,陈秉辉,赵亚飞,朱林辉.一种丙三醇氢解制一元醇的磷化物催化剂的方法[P]. CN107029765A,2017-08-11.
34. 李云华,陈思静,陈秉辉.一种利用3D打印技术辅助结构化Ni#氧化铝/碳催化剂的制备方法[P]. CN107442127A,2017-12-08.
35. 陈秉辉,彭晓芳,王子丹,张诺伟,郑进保.一种处理有机小分子的废水催化剂及其制备方法[P].CN105126871A,2015-12-09.
36. 陈秉辉,胡小燕,郑进保,张诺伟,邓湘玲,李梦溪.一种碳颗粒物燃烧催化剂及其制备方法[P].CN105597781A,2016-05-25.
37. 陈秉辉,陈翠华,郑进保,李阳,张诺伟,杨昭,孙孟玲.一种加氢异构催化剂的制备方法[P].CN105688979A,2016-06-22.
38. 陈秉辉,孙孟玲,郑进保,张诺伟,陈翠华.一种转化废水中水合肼的方法[P].CN105712463A,2016-06-29.
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六、研究动态